PNN iron pincer complex is now commercially available from Tokyo Chemical Industry (TCI). This air-stable complex exhibits high catalytic activity for C-H borylation of arenes and alkene hydrosilylation.

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See our publication for futher details:

Syntehsis

- Facile Entry to Iron Complexes Supported by Quinoline-based PNN Pincer Ligand (BCSJ, CSJ website)

C-H borylation of arenes

- Iron-catalyzed Versatile and Efficient C(sp2)-H Borylation (CL, CSJ website)

Alkene hydrosilylation

- Development of Activator-free Iron Pincer Complexes for Alkene Hydrosilylation and Elucidation of its Activation Mechanism (CL, CSJ website)

- Hemisphere and Distance-dependent Steric Analysis of PNN Iron Pincer Complexes using SambVca 2.1 and its Influence on Alkene Hydrosilylation (OM, ACS website)

Product code (TCI): D5886 (link to TCI website)

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当研究グループで開発した鉄錯体が東京化成工業（TCI）から製品化となりました。この錯体は空気に安定であり、加えて芳香族化合物のC-Hホウ素化やアルケンのヒドロシリル化反応に対して高い触媒活性を示します。利用例の詳細は論文をご参照ください。