NEDO「官民による若手研究者発掘支援事業」の共同研究フェーズに採択されました。引き続き鉄触媒を利用した有機ケイ素材料の開発を継続予定です。
Research Papers （研究論文）
2024
30. Theoretical Study on C-H Activation of Arenes Catalyzed by PNN Iron
Pincer Complex
Masahiro Kamitani,* Hidetaka Yuge
manuscript in preparation.
29. Transition Metal Complexes Supported by a Quinoline-based BiNN Pincer
Ligand
Masahiro Kamitani,* Jin Kasai, Hidetaka Yuge
manuscript in preparation.
28. Silicone Curing by Air-stable Iron Complex
Masahiro Kamitani,* Yuki Seita, Kouta Yujiri, Hidetaka Yuge
manuscript in preparation.
2023
27. Iron pivalate complexes containing PNN pincer ligand: Synthesis and
application to dehydrogenative hydrosilane coupling
Masahiro Kamitani,* Kazuki Kanemitsu, Kouta Yujiri, Hidetaka Yuge
Organometallics, 2023, 42, 1839-1848.
Special Issue: Advances and Applications in Catalysis with Earth-Abundant
Metals
DOI: 10.1021/acs.organomet.3c00161
2022
26. Earth abundant 3d transition metals (Fe, Co, Ni) for non-directed C-H
borylation
Masahiro Kamitani*
publisher: Wiley-VCH. ISBN: 9783527834242 (book chapter in Handbook of CH-Functionalization)
DOI: 10.1002/9783527834242.chf0088
2021
25. Chemically Robust and Readily Available Quinoline-based PNN Iron Complexes:
Application in C-H Borylation of Arenes
Masahiro Kamitani*
Chemical Communications, 2021, 57, 13246-13258. (Functionalization of unreactive C-H bonds)
DOI: 10.1039/D1CC04877E
2020
24. Hemisphere and Distance-dependent Steric Analysis of PNN Iron Pincer
Complexes using SambVca 2.1 and its Influence on Alkene Hydrosilylation
Masahiro Kamitani,* Kouta Yujiri, Hidetaka Yuge
Organometallics, 2020, 39, 3535-3539.
DOI: 10.1021/acs.organomet.0c00512
2019
23. Development of Activator-free Iron Pincer Complexes for Alkene Hydrosilylation
and Elucidation of its Activation Mechanism
Masahiro Kamitani,* Haruki Kusaka, Hidetaka Yuge
Chemistry Letters, 2019, 48, 1196-1198.
DOI: 10.1246/cl.190521
22. Iron-catalyzed Versatile and Efficient C(sp2)-H Borylation
Masahiro Kamitani,* Haruki Kusaka, Hidetaka Yuge
Chemistry Letters, 2019, 48, 898-901 (Open Access).
DOI: 10.1246/cl.190345
2018
21. Facile Entry to Iron Complexes Supported by Quinoline-based PNN Pincer
Ligand
Masahiro Kamitani,* Haruki Kusaka, Takumi Toriyabe and Hidetaka Yuge
Bulletin of the Chemical Society of Japan, 2018, 91, 1429-1435.
DOI: 10.1246/bcsj.20180124
20. Dihydride Iron Complex Bearing a Silyl Tethered Cyclopentadienyl Ligand
Masahiro Kamitani,* Yoshinori Nishiguchi, Masumi Itazaki, Hiroshi Nakazawa*
Bulletin of the Chemical Society of Japan, 2018, 91, 588-594. (Selected Paper, Cover Art)
DOI: 10.1246/bcsj.20170403
2017-earlier
19. Polyhydrides of Sc, Zr and Hf and Their Proposed Formation
Takashi Kurogi, Masahiro Kamitani, Patrick J. Carroll and Daniel J. Mindiola*
Israel Journal of Chemistry, 2017, 57, 999-1009.
DOI: 10.1002/ijch.201700062
18. Room Temperature Ring-Opening of Quinoline, Isoquinoline and Pyridine
with Low-Valent Titanium
Seung-yeol Baek, Takashi Kurogi, Dahye Kang, Masahiro Kamitani, Seongyeon
Kwon, Douglas P. Solowey, Chun-Hsing Chen, Maren Pink, Patrick J. Carroll,
Daniel J. Mindiola,* and Mu-Hyun Baik*
Journal of the American Chemical Society, 2017, 139, 12804-12814.
DOI: 10.1021/jacs.7b07433
17. Reactivity Studies of a Zirconium Methylidene Complex. Group Transfer
and Methylenation Reactions
Kurogi Takashi, Masahiro Kamitani, Brian C. Manor, Patrick J. Carroll,
Daniel J. Mindiola*
Organometallics, 2017, 36, 74-79.
DOI: 10.1021/acs.organomet.6b00594
16. Direct C─H Functionalization of Methane by Homogeneous Catalysis
Masahiro Kamitani*
Journal of Synthetic Organic Chemistry, Japan, 2017, 75, 1290-1291.
DOI: 10.5059/yukigoseikyokaishi.75.1290
15. Synthesis of Vinylphosphine and Unsymmetric Diphosphine: Iron-catalyzed
Selective Hydrophosphination Reaction of Alkynes and Vinylphosphines with
Secondary Phosphines
Masumi Itazaki,* Shinya Katsube, Masahiro Kamitani, Hiroshi Nakazawa*
Chemical Communications, 2016, 52, 3163-3166.
DOI: 10.1039/C5CC10185A
14. Redox and Reactivity of Cyclo-P3 Complexes of Vanadium and the Origin
of their 31P NMR Spectroscopic Chemical Shift
Balazs Pinter, Kyle T. Smith, Masahiro Kamitani, Eva M. Zolnhofer, Ba L.
Tran, Skye Fortier, Maren Pink, Gang Wu, Brian C. Manor, Karsten Meyer,*
Mu-Hyun Baik,* Daniel J. Mindiola*
Journal of the American Chemical Society2015, 137, 15247-15261.
DOI: 10.1021/jacs.5b10074
13. Phosphino-Alkylidene and -Alkylidyne Complexes of Titanium. Intermolecular
C-H Bond Activation and Dehydrogenation Reactions
Masahiro Kamitani, Balázs Pintér, Keith Searles, Marco G. Crestani, Anne
Hickey, Brian C. Manor, Patrick J. Carroll, Daniel J. Mindiola*
Journal of the American Chemical Society, 2015, 137, 11872-11875.
DOI: 10.1021/jacs.5b06973
12. beta-Hydrogen Abstraction Provides Facile Entry to Stable Titanium
and Zirconium Ethylene Complexes
Masahiro Kamitani, Keith Searles, Chun-Hsing Chen, Patrick J. Carroll,
Daniel J. Mindiola*
Organometallics, 2015, 34, 2558-2566.
DOI: 10.1021/om501226k
11. Mononuclear and Terminal Zirconium and Hafnium Methylidenes
Masahiro Kamitani, Balazs Pinter, Chun-Hsing Chen, Patrick J. Carroll and
Daniel J. Mindiola*
Angewandte Chemie International Edition, 2014, 53, 10913-10915.
DOI: 10.1002/anie.201405042 (Selected as a Hot Paper and a Cover Art)
10. Effective Dehydrogenation of 2-Pyridylmethanol Derivatives Catalyzed
by an Iron Complex
Masahiro Kamitani, Masaki Ito, Masumi Itazaki, Hiroshi Nakazawa*
Chemical Communications, 2014, 50, 7941-7944.
DOI: 10.1039/C4CC01498G
9. Synthesis of Fe-H/Si-H and Fe-H/Ge-H Bifunctional Complexes and Their
Catalytic Hydrogenation Reaction toward Non-polar Unsaturated Organic Molecules
Masahiro Kamitani, Yoshinori Nishiguchi, Ryosuke Tada, Masumi Itazaki,
Hiroshi Nakazawa*
Organometallics, 2014, 33, 1532-1535.
DOI: 10.1021/om5000562
8. Recent Researches on Hydrogen Generation Reaction Catalyzed by Group
8 Transition-Metal Complex
Masumi Itazaki,* Masahiro Kamitani
Bulletin Japan Society of Coordination Chemistry, 2013, 62, 23-26.
DOI: 10.4019/bjscc.62.23
7. Regioselective Double Hydrophosphination of Terminal Aryacetylenes Catalyzed
by an Iron Complex
Masahiro Kamitani, Masumi Itazaki, Chihiro Tamiya, Hiroshi Nakazawa*
Journal of the American Chemical Society, 2012, 134, 11932-11935.
DOI: 10.1021/ja304818c
6. Catalytic Synthesis of Cyclic and Linear Germoxanes Mediated by Iron
Complex
Masahiro Kamitani, Kozo Fukumoto, Ryosuke Tada, Masumi Itazaki, Hiroshi
Nakazawa*
Organometallics, 2012, 31, 2957-2960.
DOI: 10.1021/om3001845
5. Selective Dehydrogenativesilylation-Hydrogenation Reaction of Divinyldisiloxane
with Hydro- silane Catalyzed by an Iron Complex
Roman Naumov, Masumi Itazaki, Masahiro Kamitani, Hiroshi Nakazawa*
Journal of the American Chemical Society, 2012, 134, 804-807.
DOI: 10.1021/ja209436s
4. Trans-selective hydrogermylation of alkynes promoted by methyliron and
bis(germyl) hydridoiron complexes as a catalyst precursor
Masumi Itazaki, Masahiro Kamitani, Hiroshi Nakazawa*
Chemical Communications, 2011, 47, 7854-7856.
DOI: 10.1039/C1CC12530C
3. Synthesis, Characterization, and Crystal Structure of Germyl(phosphine)iron
Complexes, Cp(CO)Fe(PPh3)(GeR3) (R = Et, nBu, Ph), Prepared from Cp(CO)Fe
(PPh3)(Me) and HGeR3
Masumi Itazaki, Masahiro Kamitani, Yasuhiro Hashimoto, Hiroshi Nakazawa*
Phosphorus, Sulfur, and Silicon and the Related Elements, 2010, 185, 1054-1060.
DOI:10.1080/10426501003773373
2. Syntheses and Ligand Exchange Reaction of Iron(IV) Complexes with Two
Different Group 14 Element Ligands, Cp(CO)FeH(EEt3)(E’Et3) (E, E’ = Si,
Ge, Sn)
Masumi Itazaki, Masahiro Kamitani, Kensuke Ueda, Hiroshi Nakazawa*
Organometallics, 2009, 28, 3601-3603.
DOI: 10.1021/om900225x
1. Carbonyl(η5-cyclopentadienyl)(pyridine)(triethylstannyl)iron(II)
Masumi Itazaki, Masahiro Kamitani, Hiroshi Nakazawa*
Acta Crystallographica Section E, 2008, 64, m1578.
DOI: 10.1107/S1600536808037781
PATENT （特許）
2. 神谷昌宏、「鉄錯体化合物およびその製造方法、ならびに有機ケイ素化合物の製造方法」
1. 神谷昌宏、「３座配位子を有する鉄錯体化合物の製造方法、並びに有機ボロン酸エステルの製造方法」、、特許7220902
MISCELLANEOUS（その他、新聞報道等、査読のない研究記事）
11. ヘテロ原子含有有機ケイ素部材の製造技術開発、NEDOマッチングイベント（youtube 動画）
10.Contribution of computational methods to catalyst development, Masahiro Kamitani,* Open Access Government, 2022, 34 (Apr), 252-253. website
9. Chemistry: Catalyst developments for organic synthesis, Masahiro Kamitani,* Open Access Government, 2022, 33 (Jan), 212-213. website
8. Replacing platinum catalysts with iron catalysts for silicone production, Masahiro Kamitani,* Open Access Government, 2021, 32 (Oct), 258-259. website
7. Improvements in chemical processes using iron catalysts, Masahiro Kamitani,* Open Access Government, 2021, 31 (July), 268-269. website
6. The Kamitani research group – Improving industrial reactions using iron, Open Access Government, website
5. 高機能な有機ケイ素材料の製造に適した鉄錯体触媒の開発に成功 ―空気中で安定な鉄触媒として東京化成工業から発売―（Press Release, Dec 14, 2020）
関連紙面記事 (printed newspaper)：
- 有機ケイ素材料 高機能化、安価提供へ（電波新聞, Dec 25, 2020）
- 有機ケイ素材料に適した鉄錯体触媒 NEDO など（化学工業日報, Dec 18, 2020）
- 鉄錯体触媒を開発－高活性、白金代替に－（日刊産業新聞, Jan 20, 2021）
4. PNN iron pincer complex:TCI product page, D5886
3. Focusing on the research work undertaken in the Kamitani Group (Oct 01, 2020) Website
2. 近畿化学協会有機金属部会 海外研究室レポート（ペンシルバニア大学、Mindiola教授研究室）, 神谷昌宏, OMnews 2018, 3, 93-94. website
1. 2 つの 14 族配位子を有する 4 価鉄錯体における配位子置換反応, Bulletin of Japan Society of Coordination Chemistry, 2008, 53, 62-64.